Lifeboat Foundation

For the first time, Stanford researchers have found a way to create and stabilize an extremely rare form of gold that has lost two negatively charged electrons, denoted Au²⁺. The material stabilizing this elusive version of the valued element is a halide perovskite—a class of crystalline materials that holds great promise for various applications including more-efficient solar cells, light sources, and electronics components.

Surprisingly, the Au²⁺ perovskite is also quick and simple to make using off-the-shelf ingredients at room temperature.

“It was a real surprise that we were able to synthesize a stable material containing Au²⁺ —I didn’t even believe it at first,” said Hemamala Karunadasa, associate professor of chemistry at the Stanford School of Humanities and Sciences and senior author of the study published Aug. 28 in Nature Chemistry. “Creating this first-of-its-kind Au²⁺ perovskite is exciting. The gold atoms in the perovskite bear strong similarities to the copper atoms in high-temperature superconductors, and heavy atoms with unpaired electrons, like Au²⁺, show cool magnetic effects not seen in lighter atoms.”