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Clearest evidence yet that giant planets spin faster than their cosmic lookalikes

For decades, astronomers have struggled to differentiate giant planets from brown dwarfs, a class of objects more massive than planets but too small to ignite nuclear fusion like true stars. Through a telescope, these cosmic lookalikes can have overlapping brightness, temperatures, and even atmospheric fingerprints. The striking similarity leaves astronomers unsure if they have observed an oversized planet or an undersized star. Now, a Northwestern University-led team has uncovered a crucial clue that separates the two: how fast they spin.

In a new study, astrophysicists found the clearest evidence yet that giant planets spin significantly faster than their brown dwarf counterparts. The new results suggest rotation measurements may provide a powerful new diagnostic for classifying these indistinguishable populations and suggest that these two objects evolve differently, perhaps even forming through distinct processes.

The study was published in The Astronomical Journal. It marks the largest survey of spin measurements of directly imaged extrasolar planets and brown dwarfs to date.

The Effect of Exogenous Acid Identity on Iron Tetraphenylporphyrin-Catalyzed CO2 ReductionClick to copy article linkArticle link copied!

‘The Effect of Exogenous Acid Identity on Iron Tetraphenylporphyrin-Catalyzed CO2 Reduction’ from Inorganic Chemistry is currently free to read as an ACSEditorsChoice.

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Iron tetraphenylporphyrin (FeTPP) is a privileged electrocatalyst for the 2e–/2H+ reduction of CO2 to CO. FeTPP-catalyzed CO2 reduction typically employs phenol as an exogenous acid to promote the rate-limiting proton-coupled electron transfer. Beyond the observation that catalytic rates increase with decreasing pKa, the effects of acid identity on reaction kinetics are largely unexplored. Herein, we report rates of FeTPP-catalyzed CO2 reduction with structurally diverse O–H, N–H, and C–H acids. While many of these acids follow the expected Brønsted relationship, there are several notable exceptions: the fluorinated alcohols hexafluoroisopropanol (log(kcat) = 4.54) and 2,2,2-trifluoroethanol (log(kcat) = 3.55)─and the N–H acid imidazole (log(kcat) = 4.41)─display catalytic rates that are several times greater than rates obtained with similarly acidic phenols. Amides with pKas 19 (in dimethyl sulfoxide) display similar activity as comparably acidic O–H acids, while rates obtained with less acidic amides are ∼2 orders of magnitude slower than O–H donors of similar pKa. Each C–H acid affords poor activity. An Eyring analysis suggests that acids enforcing less ordered transition states afford superior kinetics. This study reveals that acid pKa is only one relevant parameter for altering catalytic rates, and judicious selection of the acid is crucial for enhancing catalytic rates.

Orbital Farms

As humanity expands into space, we’ll need new ways to grow food. Explore how orbital farms could sustain billions—on Earth, Mars, and beyond.

Checkout Scav: https://go.nebula.tv/scav?ref=isaacar… Watch my exclusive video Autonomous Space Industry: https://nebula.tv/videos/isaacarthur–… Nebula using my link for 40% off an annual subscription: https://go.nebula.tv/isaacarthur Grab one of our new SFIA mugs and make your morning coffee a little more futuristic — available now on our Fourthwall store! https://isaac-arthur-shop.fourthwall… Visit our Website: http://www.isaacarthur.net Join Nebula: https://go.nebula.tv/isaacarthur Support us on Patreon: / isaacarthur Support us on Subscribestar: https://www.subscribestar.com/isaac-a… Facebook Group: / 1,583,992,725,237,264 Reddit: / isaacarthur Twitter: / isaac_a_arthur on Twitter and RT our future content. SFIA Discord Server: / discord Credits: Orbital Farms — Extended Edition Episode 471a; November 1, 2024 Produced, Narrated & Written: Isaac Arthur Graphics: Jarred Eagley Jeremy Jozwik Katie Byrne Ken York YD Visual Udo Schroeter Select imagery/video supplied by Getty Images Music Courtesy of Epidemic Sound http://epidemicsound.com/creator.
Watch my exclusive video Autonomous Space Industry: https://nebula.tv/videos/isaacarthur–
Get Nebula using my link for 40% off an annual subscription: https://go.nebula.tv/isaacarthur.

Grab one of our new SFIA mugs and make your morning coffee a little more futuristic — available now on our Fourthwall store! https://isaac-arthur-shop.fourthwall

Visit our Website: http://www.isaacarthur.net.
Join Nebula: https://go.nebula.tv/isaacarthur.
Support us on Patreon: / isaacarthur.
Support us on Subscribestar: https://www.subscribestar.com/isaac-a
Facebook Group: / 1583992725237264
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Twitter: / isaac_a_arthur on Twitter and RT our future content.
SFIA Discord Server: / discord.
Credits:
Orbital Farms — Extended Edition.
Episode 471a; November 1, 2024
Produced, Narrated & Written: Isaac Arthur.
Graphics:
Jarred Eagley.
Jeremy Jozwik.
Katie Byrne.
Ken York YD Visual.
Udo Schroeter.
Select imagery/video supplied by Getty Images.
Music Courtesy of Epidemic Sound http://epidemicsound.com/creator

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Why Hollywood Is Facing a Very Unhappy Ending

Layoffs, consolidation, streaming losses, artificial intelligence and the rise of the creator economy are reshaping Hollywood, raising questions about whether the industry is just hitting a rough patch or in terminal decline.

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China succeeds in mimicking photosynthesis and transforming CO₂ and water into fuel: the experiment that could revolutionize the production of synthetic gasoline

Could future gasoline come from thin air and sunlight instead of oil wells? A team of Chinese scientists has unveiled a lab system that imitates plant photosynthesis to turn carbon dioxide and water into gasoline building blocks using only sunlight. Their work hints at a way to recycle a major greenhouse gas while still using existing engines and fuel infrastructure.

In an artificial photosynthesis study, the researchers report a “charge reservoir” material that stores solar energy as electrical charge, then delivers it on demand to drive reactions. The system converts carbon dioxide into carbon monoxide, a key building block for synthetic fuels, and uses water as its only electron source instead of extra helper chemicals.

Although still a lab device, the setup works under natural sunlight and is meant to connect renewable energy to industry and transport.

How an acid found in grapes could help recycle battery metals

Cobalt and nickel are vital components for batteries, superalloys and catalysts, used in technologies ranging from smartphones to jet engines. But when it comes to recycling, they are notoriously difficult to separate because they are chemically nearly identical. To solve this, a team led by scientists at Johns Hopkins University in the United States has developed a cleaner and cheaper way to extract these elements. And it is thanks in part to grapes.

From guesswork to guidance: How machine learning speeds dopant design for water-splitting photocatalysts

MLIP calculations successfully identify suitable dopants for a novel photocatalytic material, report researchers from the Institute of Science Tokyo. As demonstrated in their study, published in the Journal of the American Chemical Society, a materials informatics approach could predict which ions can be stably introduced into orthorhombic Sn3O4, a promising and recently discovered photocatalytic tin oxide.

Their experiments revealed that aluminum-doped samples achieved 16 times greater hydrogen production than the undoped material, paving the way for next-generation clean energy applications.

Building a sustainable hydrogen economy requires clean and efficient ways to produce hydrogen at scale. One particularly attractive approach is photocatalysis—using materials called photocatalysts to split water into hydrogen and oxygen utilizing sunlight.

Fundamental constraints to the logic of living systems

Excellent review in which Solé et al. explore how physical/mathematical constraints may determine what subset of biological systems could theoretically evolve in the universe. Lots of fascinating ideas applying concepts like Turing machines, cellular automata, McCulloch-Pitts networks, energy minimization, and phase transitions to multiscale biological and evolutionary phenomena!

I found the description of how parasites almost inevitably emerge and drive increased biodiversity in computational models of evolution particularly fascinating. Interestingly, I recall this idea was featured in the Hyperion Cantos novels during an explanation of the history of artificial intelligence in their fictional universe!


Abstract. It has been argued that the historical nature of evolution makes it a highly path-dependent process. Under this view, the outcome of evolutionary dynamics could have resulted in organisms with different forms and functions. At the same time, there is ample evidence that convergence and constraints strongly limit the domain of the potential design principles that evolution can achieve. Are these limitations relevant in shaping the fabric of the possible? Here, we argue that fundamental constraints are associated with the logic of living matter. We illustrate this idea by considering the thermodynamic properties of living systems, the linear nature of molecular information, the cellular nature of the building blocks of life, multicellularity and development, the threshold nature of computations in cognitive systems and the discrete nature of the architecture of ecosystems. In all these examples, we present available evidence and suggest potential avenues towards a well-defined theoretical formulation.

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