Lifeboat Foundation

The challenge of regulating the electronic structures of metal single-atoms (M-SAs) with metal nanoparticles (M-NPs) lies in the synthesis of a definite architecture. Such a structure has strong electronic metal-support interactions and maintains electron transport channels to facilitate carbon dioxide photoreduction (CO₂PR).

In a study published in Advanced Powder Materials, a group of researchers from Zhejiang Normal University, Zhejiang A&F University and Dalian University of Technology, revealed the engineering of the electron density of Pd single atoms with twinned Pd nanoparticles assisted by strong electronic interaction of the atomic metal with the support and unveiled the underlying mechanism for expedited CO₂PR.

“As one of the most promising CO₂PR semiconductors, polymeric graphitic carbon nitride (g-C₃N₄) featured with sp² π-conjugated lamellar structures can offer electronegative nitrogen atoms to anchor M-SAs, forming active metal-nitrogen moieties (M–N_x),” explained Lei Li, lead author of the study. “However, stable M–N_x configurations forbid tunability of electronic structures of M-SA sites.”