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Category: chemistry – Page 241

Biotechnology is creating ethical worries—and we’ve been here before

Matthew Cobb is a zoologist and author whose background is in insect genetics and the history of science. Over the past decade or so, as CRISPR was discovered and applied to genetic remodeling, he started to get concerned—afraid, actually—about three potential applications of the technology. He’s in good company: Jennifer Doudna, who won the Nobel Prize in Chemistry in 2020 for discovering and harnessing CRISPR, is afraid of the same things. So he decided to delve into these topics, and As Gods: A Moral History of the Genetic Age is the result.

Summing up fears

The first of his worries is the notion of introducing heritable mutations into the human genome. He Jianqui did this to three human female embryos in China in 2018, so the three girls with the engineered mutations that they will pass on to their kids (if they’re allowed to have any) are about four now. Their identities are classified for their protection, but presumably their health is being monitored, and the poor girls have probably already been poked and prodded incessantly by every type of medical specialist there is.

Revolutionary technique to generate hydrogen more efficiently from water

A team of researchers from the National University of Singapore (NUS) have made a serendipitous scientific discovery that could potentially revolutionize the way water is broken down to release hydrogen gas—an element crucial to many industrial processes.

The team, led by Associate Professor Xue Jun Min, Dr. Wang Xiaopeng and Dr. Vincent Lee Wee Siang from the Department of Materials Science and Engineering under the NUS College of Design and Engineering (NUS CDE), found that light can trigger a new mechanism in a catalytic material used extensively in , where water is broken down into and oxygen. The result is a more energy-efficient method of obtaining hydrogen.

This breakthrough was achieved in collaboration with Dr. Xi Shibo from the Institute of Sustainability for Chemicals, Energy and Environment under the Agency for Science, Technology and Research (A*STAR); Dr. Yu Zhigen from the Institute of High Performance Computing under A*STAR; and Dr. Wang Hao from the Department of Mechanical Engineering under the NUS CDE.

Penguin feathers may be secret to effective anti-icing technology

Ice buildup on powerlines and electric towers brought the northern US and southern Canada to a standstill during the Great Ice Storm of 1998, leaving many in the cold and dark for days and even weeks. Whether it is on wind turbines, electric towers, drones, or airplane wings, dealing with ice buildup typically depends on techniques that are time consuming, costly and/or use a lot of energy, along with various chemicals. But, by looking to nature, McGill researchers believe that they have found a promising new way of dealing with the problem. Their inspiration came from the wings of Gentoo penguins who swim in the ice-cold waters of the south polar region, with pelts that remain ice-free even when the outer surface temperature is well below freezing.

We initially explored the qualities of the lotus leaf, which is very good at shedding water but proved less effective at shedding ice,” said Anne Kietzig, who has been looking for a solution for close to a decade. She is an associate professor in Chemical Engineering at McGill and the director of the Biomimetic Surface Engineering Laboratory. “It was only when we started investigating the qualities of penguin feathers that we discovered a material found in nature that was able to shed both water and ice.”

Study involving CU-Boulder shows fertilizer can be made from sunlight

A group of scientists led by the U.S. Department of Energy’s National Renewable Energy Laboratory (NREL) in Golden and involving the University of Colorado Boulder has developed a new, eco-friendly method to produce ammonia, the main ingredient of fertilizer, using light.

The researchers discovered that light energy can be used to change dinitrogen (N2), a molecule made of two nitrogen atoms, to ammonia (NH3), a compound of nitrogen and hydrogen. The researchers hope the newly discovered, light-driven chemical process that creates ammonia can lead to future developments that will enhance global agricultural practices while decreasing the dependence of farmers on fossil fuels.

Traditionally there have been two main ways to transform nitrogen, the most common gas in Earth’s atmosphere, for use by living organisms. One is a biological process that occurs when atmospheric nitrogen is “fixed” by bacteria found in the roots of some plants like legumes and then converted to ammonia by an enzyme called nitrogenase.

Darwin’s Extraterrestrials

“By now it has become a common futurist prediction and science fiction plot device that intelligent and sentient life forms can be created which are not biochemical in nature and are thus fundamentally different from all currently known life,” distinguished Princeton astrophysicist Edwin Turner wrote in an email to The Daily Galaxy. “Whether or not this would actually be possible,” he explains, “depends on the nature and origin of consciousness, a topic about which we have little more than entertaining whistling-in-the-dark guesses at this point and no clear path toward obtaining any better understanding of this deep mystery.”

Aliens Shaped by Natural Selection

In a landmark 2017 study published in the International Journal of Astrobiology scientists from the University of Oxford showed that aliens are potentially shaped by the same processes and mechanisms that shaped humans, such as natural selection and are like us, evolving to be fitter and stronger over time.

Blood pressure medication recalled due to chemicals’ possible link to cancer

Two lots of quinapril and hydrochlorothiazide tablets have been recalled due to the presence of nitrosamines, according to a notice posted on the Food and Drug Administration’s website.

Nitrosamines are common in water and foods, including cured and grilled meats, dairy products and vegetables and may increase the risk of cancer if people are exposed to them above acceptable levels over long periods of time.

The pink, round tablets contain 20 milligrams of quinapril and 12.5 milligrams of hydrochlorothiazide and are supplied in 90-count bottles with an expiration date of January 2023. The drug is used to treat hypertension and lower blood pressure.

Bound NASA instrument preparing to brave the harsh atmosphere

NASA scientists are preparing to paint the most detailed picture to date of the atmosphere of Venus when the aptly named DAVINCI — or Deep Atmosphere Venus Investigation of Noble Gases, Chemistry, and Imaging — mission drops a probe to the planet’s surface.

When the 3-foot-wide (0.9 meters) descent sphere of the DAVINCI mission takes its one-way parachute trip to Venus’ surface in the early 2030s, it will be carrying the VASI (Venus Atmospheric Structure Investigation) instrument along with five other instruments. VASI will collect data regarding the temperature, pressure and winds of Venus’ atmosphere as it makes its hellish descent and enters the planet’s crushing lower atmosphere.

2D nanoconfinement strategy enhances oxygen evolution performances

Prof. Zhang Tao’s group at the Ningbo Institute of Materials Technology and Engineering (NIMTE) of the Chinese Academy of Sciences (CAS), in collaboration with Prof. Hou Yang from Zhejiang University and Prof. Xiao Jianping from the Dalian Institute of Chemical Physics of CAS, proposed a novel two-dimensional (2D) nanoconfinement strategy to strongly enhance the oxygen evolution reaction (OER) activity of low-conductivity metal-organic frameworks (MOFs). Results were published in Nature Communications.

The development of high-efficiency electrocatalysts for the electrochemical conversion of water to generate environmentally friendly and sustainable hydrogen energy has drawn tremendous attention for decades.

Despite the crucial role the OER plays in water splitting, OER at the anode requires a relatively high thermodynamic potential to accelerate water splitting kinetics. Thanks to the large surface area, tunable porosity, diverse compositions and metal centers, MOFs have emerged as promising candidates for efficient OER electrocatalysts. However, the intrinsically poor conductivity of the most MOFs seriously impede their .

Study shows hazardous herbicide chemical goes airborne

“Dicamba drift”—the movement of the herbicide dicamba off crops through the atmosphere—can result in unintentional damage to neighboring plants. To prevent dicamba drift, other chemicals, typically amines, are mixed with dicamba to “lock” it in place and prevent it from volatilizing, or turning into a vapor that more easily moves in the atmosphere.

Now, new research from the lab of Kimberly Parker, an assistant professor of energy, environmental and chemical engineering at Washington University in St. Louis’ McKelvey School of Engineering, has shed new light on this story by demonstrating for the first time that these themselves volatilize, often more than dicamba itself.

Their findings were published Sept. 23 in the journal Environmental Science and Technology.

FDA says it causes cancer. Yet it’s in hundreds of candies

It’s illegal to use the carcinogenic color additive Red 3 in cosmetics, such as lipsticks or blush, or externally applied drugs. Yet the discredited chemical is lurking in common varieties of candy corn, Nerds, Peeps, Pez, SweeTarts, and hundreds of candies, cakes, and other foods, including dozens of seasonal Halloween items. That’s why the Center for Science in the Public Interest and 23 other organizations and prominent scientists are today urging the Food and Drug Administration to formally remove Red 3 from the list of approved color additives in foods, dietary supplements, and oral medicines.

Since the early 1980s FDA had evidence that Red 3 caused cancer in laboratory animals. The National Toxicology Program considered the evidence “convincing.” As a result, in 1990, the agency eliminated certain “provisionally listed” uses of the chemical—meaning cosmetics and externally applied drugs. In 1990, FDA also said it would “take steps” to ban its use in foods, ingested drugs, and supplements. But those steps were never taken.

“Halloween has never been the healthiest holiday, but few parents would believe that the FDA permits the use of a dye it acknowledges as a carcinogen to be used as a common ingredient in candy,” said CSPI consultant Lisa Y. Lefferts. “Fewer still would believe that the FDA prohibits this carcinogen in makeup but allows it in food.”