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Archive for the ‘chemistry’ category: Page 245

Mar 22, 2021

Plasmonic nanoreactors regulate selective oxidation via energetic electrons and nanoconfined thermal fields

Posted by in categories: chemistry, energy, engineering, nanotechnology

When optimizing catalysis in the lab, product selectivity and conversion efficiency are primary goals for materials scientists. Efficiency and selectivity are often mutually antagonistic, where high selectivity is accompanied by low efficiency and vice versa. Increasing the temperature can also change the reaction pathway. In a new report, Chao Zhan and a team of scientists in chemistry and chemical engineering at the Xiamen University in China and the University of California, Santa Barbara, U.S., constructed hierarchical plasmonic nanoreactors to show nonconfined thermal fields and electrons. The combined attributes uniquely coexisted in plasmonic nanostructures. The team regulated parallel reaction pathways for propylene partial oxidation and selectively produced acrolein during the experiments to form products that are different from thermal catalysis. The work described a strategy to optimize chemical processes and achieve high yields with high selectivity at lower temperature under visible light illumination. The work is now published on Science Advances.

Catalysts

Ideal catalytic processes can produce desired target products without undesirable side effects under cost-effective conditions, although such conditions are rarely achieved in practice. For instance, high efficiency and high selectivity are antagonistic goals, where a relatively high temperature is often necessary to overcome the large barrier of oxygen activation to achieve high reactant conversion. Increasing the functional temperature can also lead to overoxidized and therefore additional byproducts. As a result, researchers must compromise between selectivity and efficiency. For instance, a given molecule typically requires diverse catalysts to generate different products, where each catalyst has different efficiency and selectivity. To circumvent any limitations, they can use surface plasmons (SPs) to redistribute photons, electrons and heat energy in space and time.

Mar 22, 2021

Action potentials induce biomagnetic fields in carnivorous Venus flytrap plants

Posted by in categories: biotech/medical, chemistry, neuroscience, quantum physics

“Previously reported detection of plant biomagnetism, which established the existence of measurable magnetic activity in the plant kingdom, was carried out using superconducting-quantum-interference-device (SQUID) magnetometers1, 5, 16. Atomic magnetometers are arguably more attractive for biological applications, since, unlike SQUIDs34, 35, they are non-cryogenic and can be miniaturized to optimize spatial resolution of measured biological features14, 15, 36. In the future, the SNR of magnetic measurements in plants will benefit from optimizing the low-frequency stability and sensitivity of atomic magnetometers. Just as noninvasive magnetic techniques have become essential tools for medical diagnostics of the human brain and body, this noninvasive technique could also be useful in the future for crop-plant diagnostics—by measuring the electromagnetic response of plants facing such challenges as sudden temperature change, herbivore attack, and chemical exposure.”


Upon stimulation, plants elicit electrical signals that can travel within a cellular network analogous to the animal nervous system. It is well-known that in the human brain, voltage changes in certain regions result from concerted electrical activity which, in the form of action potentials (APs), travels within nerve-cell arrays. Electro-and magnetophysiological techniques like electroencephalography, magnetoencephalography, and magnetic resonance imaging are used to record this activity and to diagnose disorders. Here we demonstrate that APs in a multicellular plant system produce measurable magnetic fields. Using atomic optically pumped magnetometers, biomagnetism associated with electrical activity in the carnivorous Venus flytrap, Dionaea muscipula, was recorded. Action potentials were induced by heat stimulation and detected both electrically and magnetically.

Mar 19, 2021

Chemical cocktail creates new avenues for generating muscle stem cells

Posted by in categories: biotech/medical, chemistry

A UCLA-led research team has identified a chemical cocktail that enables the production of large numbers of muscle stem cells, which can self-renew and give rise to all types of skeletal muscle cells.

Mar 16, 2021

Discovery identifies non-DNA mechanism involved in transmitting paternal experience to offspring

Posted by in categories: biotech/medical, chemistry, health

It has long been understood that a parent’s DNA is the principal determinant of health and disease in offspring. Yet inheritance via DNA is only part of the story; a father’s lifestyle such as diet, being overweight and stress levels have been linked to health consequences for his offspring. This occurs through the epigenome—heritable biochemical marks associated with the DNA and proteins that bind it. But how the information is transmitted at fertilization along with the exact mechanisms and molecules in sperm that are involved in this process has been unclear until now.

A new study from McGill, published recently in Developmental Cell, has made a significant advance in the field by identifying how is transmitted by non-DNA molecules in the sperm. It is a discovery that advances scientific understanding of the heredity of paternal life experiences and potentially opens new avenues for studying disease transmission and prevention.

Mar 16, 2021

Exploring complex graphs using three-dimensional quantum walks of correlated photons

Posted by in categories: biological, chemistry, information science, internet, quantum physics, space travel

Graph representations can solve complex problems in natural science, as patterns of connectivity can give rise to a magnitude of emergent phenomena. Graph-based approaches are specifically important during quantum communication, alongside quantum search algorithms in highly branched quantum networks. In a new report now published on Science Advances, Max Ehrhardt and a team of scientists in physics, experimental physics and quantum science in Germany introduced a hitherto unidentified paradigm to directly realize excitation dynamics associated with three-dimensional networks. To accomplish this, they explored the hybrid action of space and polarization degrees of freedom of photon pairs inside complex waveguide circuits. The team experimentally explored multiparticle quantum walks on complex and highly connected graphs as testbeds to pave the way to explore the potential applications of fermionic dynamics in integrated photonics.

Complex networks

Complex networks can occur across diverse fields of science, ranging from biological signaling pathways and biochemical molecules to exhibit efficient energy transport to neuromorphic circuits across to social interactions across the internet. Such structures are typically modeled using graphs whose complexity relies on the number of nodes and linkage patterns between them. The physical representation of a graph is limited by their requirement for arrangement in three-dimensional (3D) space. The human brain is a marked example of scaling behavior that is unfavorable for physical simulation due to its staggering number of 80 billion neurons, dwarfed by 100 trillion synapses that allow the flow of signals between them. Despite the number of comparably miniscule volume of nodes, discrete quantum systems faced a number of challenges owing to complex network topologies, efficient multipartite quantum communications and search algorithms.

Mar 15, 2021

Twisting, flexible crystals key to solar energy production

Posted by in categories: chemistry, solar power, sustainability

Researchers at Duke University have revealed long-hidden molecular dynamics that provide desirable properties for solar energy and heat energy applications to an exciting class of materials called halide perovskites.

A key contributor to how these materials create and transport electricity literally hinges on the way their atomic lattice twists and turns in a hinge-like fashion. The results will help materials scientists in their quest to tailor the chemical recipes of these materials for a wide range of applications in an environmentally friendly way.

The results appear online March 15 in the journal Nature Materials.

Mar 12, 2021

NASA shares first recording of Perseverance firing its laser on Mars

Posted by in categories: chemistry, space

The sounds of 30 impacts are heard, some slightly louder than others, said NASA in its press release. SuperCam, equipped with a microphone, is using the laser to interrogate the composition of rock on the red planet. The variations in the zapping sound picked up the equipment would help the scientists in understanding the physical structure of the rocks and is a key component in probing the signs of ancient life.

“Variation in the intensity of the zapping sounds will provide information on the physical structure of the targets, such as its relative hardness or the presence of weathering coatings,” said NASA.

Continue reading “NASA shares first recording of Perseverance firing its laser on Mars” »

Mar 11, 2021

Explaining the Quirks of the Universe: “Search of a Lifetime” for Supersymmetric Particles at CERN

Posted by in categories: chemistry, particle physics

University of Chicago researchers hunt for proposed particles that could explain quirks of the universe.

A team of researchers at the University of Chicago recently embarked on the search of a lifetime—or rather, a search for the lifetime of long-lived supersymmetric particles.

Supersymmetry is a proposed theory to expand the Standard Model of particle physics. Akin to the periodic table of elements, the Standard Model is the best description we have for subatomic particles in nature and the forces acting on them.

Mar 9, 2021

Key step reached to­ward long-​sought goal of a silicon-​based laser

Posted by in categories: chemistry, computing, quantum physics

When it comes to microelectronics, there is one chemical element like no other: silicon, the workhorse of the transistor technology that drives our information society. The countless electronic devices we use in everyday life are a testament to how today very high volumes of silicon-based components can be produced at very low cost. It seems natural, then, to use silicon also in other areas where the properties of semiconductors—as silicon is one—are exploited technologically, and to explore ways to integrate different functionalities. Of particular interest in this context are diode lasers, such as those employed in barcode scanners or laser pointers, which are typically based on gallium arsenide (GaAs). Unfortunately though, the physical processes that create light in GaAs do not work so well in silicon. It therefore remains an outstanding, and long-standing, goal to find an alternative route to realizing a ‘laser on silicon.’

Writing today in Applied Physics Letters, an international team led by Professors Giacomo Scalari and Jérôme Faist from the Institute for Quantum Electronics present an important step towards such a device. They report electroluminescence—electrical light generation—from a based on silicon-germanium (SiGe), a material that is compatible with standard fabrication processes used for silicon devices. Moreover, the emission they observed is in the terahertz frequency band, which sits between those of microwave electronics and infrared optics, and is of high current interest with a view to a variety of applications.

Mar 8, 2021

Bacteria Reprogrammed to Make Designer Molecule Used in Pharmaceutical Drugs

Posted by in categories: biotech/medical, chemistry, engineering, genetics

Envisioning an animal-free drug supply, scientists have — for the first time — reprogrammed a common bacterium to make a designer polysaccharide molecule used in pharmaceuticals and nutraceuticals. Published on March 22021, in Nature Communications, the researchers modified E. coli to produce chondroitin sulfate, a drug best known as a dietary supplement to treat arthritis that is currently sourced from cow trachea.

Genetically engineered E. coli is used to make a long list of medicinal proteins, but it took years to coax the bacteria into producing even the simplest in this class of linked sugar molecules — called sulfated glycosaminoglycans — that are often used as drugs and nutraceuticals…

“It’s a challenge to engineer E. coli to produce these molecules, and we had to make many changes and balance those changes so that the bacteria will grow well,” said Mattheos Koffas, lead researcher and a professor of chemical and biological engineering at Rensselaer Polytechnic Institute. “But this work shows that it is possible to produce these polysaccharides using E. coli in animal-free fashion, and the procedure can be extended to produce other sulfated glycosaminoglycans.”