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Category: chemistry – Page 37

We are made out of functions, and those functions are made out of functions, all the way down.

Even bacteria—the simplest life forms surviving today—are a product of many subsequent evolutionary steps.

IX. Ecology

Fundamentally, life is code, and code is life. More precisely, individual computational instructions are the irreducible quanta of life—the minimal replicating set of entities, however immaterial and abstract they may seem, that come together to form bigger, more stable, and more complex replicators, in ever-ascending symbiotic cascades.

Continue reading “In the Beginning, There Was Computation” | >

A new technology can extract lithium from brines at an estimated cost of under 40% that of today’s dominant extraction method, and at just a fourth of lithium’s current market price. The new technology would also be much more reliable and sustainable in its use of water, chemicals, and land than today’s technology, according to a study published in Matter by Stanford University researchers.

Global demand for lithium has surged in recent years, driven by the rise of electric vehicles and renewable energy storage. The dominant source of lithium extraction today relies on evaporating brines in huge ponds under the sun for a year or more, leaving behind a lithium-rich solution, after which heavy use of potentially toxic chemicals finishes the job. Water with a high concentration of salts, including lithium, occurs naturally in some lakes, hot springs, and aquifers, and as a byproduct of oil and natural gas operations and of .

Many scientists are searching for less expensive and more efficient, reliable, and environmentally friendly lithium extraction methods. These are generally direct lithium extraction that bypasses big evaporation ponds. The new study reports on the results of a new method using an approach known as “redox-couple electrodialysis,” or RCE, along with cost estimates.

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Can biology be explained entirely in terms of chemistry and then physics? If so, that’s “reductionism.” Or are there “emergent” properties at higher levels of the hierarchy of life that cannot be explained by properties at lower or more basic levels?

Watch more videos on the philosophy of biology: https://shorturl.at/0D92A

Michael Ruse is the Lucyle T. Wekmeister Professor and Director of the History and Philosophy of Science Program at Florida State University.

Continue reading “Michael Ruse — Philosophy of Reductionism & Emergence” | >

The distribution of outermost shell electrons, known as valence electrons, of organic molecules was experimentally observed for the first time by a team led by Nagoya University in Japan. As the interactions between atoms are governed by the valence electrons, their findings shine light on the fundamental nature of chemical bonds, with implications for pharmacy and chemical engineering. The results were published in the Journal of the American Chemical Society.

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The new research harnesses previously unknown features of this ancient viral DNA, creating a biological clock to track a person’s age from the DNA’s chemical changes.

And the researchers now believe that new antiretroviral therapies, similar to those used to fight the HIV virus and AIDS, might one day help reverse the signs of aging.

‘Our findings indicate that retroelement clocks capture previously undetected facets of biological aging,’ said study co-author Dr Michael Corley, an assistant professor of immunology at Weill Cornell Medicine in New York.

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Engineers have designed a tiny battery, smaller than a grain of sand, to power microscopic robots for jobs such as drug delivery or locating leaks in gas pipelines.

A tiny battery designed by MIT engineers could enable the deployment of cell-sized, autonomous robots for drug delivery within in the human body, as well as other applications such as locating leaks in gas pipelines.

The new battery, which is 0.1 millimeters long and 0.002 millimeters thick — roughly the thickness of a human hair — can capture oxygen from air and use it to oxidize zinc, creating a current with a potential of up to 1 volt. That is enough to power a small circuit, sensor, or actuator, the researchers showed.

“We think this is going to be very enabling for robotics,” says Michael Strano, the Carbon P. Dubbs Professor of Chemical Engineering at MIT and the senior author of the study. “We’re building robotic functions onto the battery and starting to put these components together into devices.”

Continue reading “MIT engineers design tiny batteries for powering cell-sized robots” | >

A view into how nanoscale building blocks can rearrange into different organized structures on command is now possible with an approach that combines an electron microscope, a small sample holder with microscopic channels, and computer simulations, according to a new study by researchers at the University of Michigan and Indiana University.

The approach could eventually enable smart materials and coatings that can switch between different optical, mechanical and electronic properties.

“One of my favorite examples of this phenomenon in nature is in chameleons,” said Tobias Dwyer, U-M doctoral student in chemical engineering and co-first author of the study published in Nature Chemical Engineering (“Engineering and direct imaging of nanocube self-assembly pathways”). “Chameleons change color by altering the spacing between nanocrystals in their skin. The dream is to design a dynamic and multifunctional system that can be as good as some of the examples that we see in biology.”

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Harvard researchers have shown that quantum coherence can survive chemical reactions at ultracold temperatures. Using advanced techniques, they demonstrated this with 40K87Rb bialkali molecules, suggesting potential applications in quantum information science and broader implications for understanding chemical reactions.

Zoom in on a chemical reaction to the quantum level and you’ll notice that particles behave like waves that can ripple and collide. Scientists have long sought to understand quantum coherence, the ability of particles to maintain phase relationships and exist in multiple states simultaneously; this is akin to all parts of a wave being synchronized. It has been an open question whether quantum coherence can persist through a chemical reaction where bonds dynamically break and form.

Now, for the first time, a team of Harvard scientists has demonstrated the survival of quantum coherence in a chemical reaction involving ultracold molecules. These findings highlight the potential of harnessing chemical reactions for future applications in quantum information science.

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ABOVE: Researchers recapitulate electrical gradients in vitro to help guide stem cell differentiation for neural regeneration. ©istock, Cappan.

The dance of development is electric. Bioelectrical gradients choreograph embryonic growth, signaling to stem cells what cell types they should become, where they should travel, who their neighbors should be, and what structures they should form.1 The intensity and location of these signals serve as an electrical scaffold to map out anatomical features and guide development. Bioelectricity also shapes tissue regeneration.2 Tapping into these mechanisms is of special interest to researchers who grapple with the challenge of regenerating injured nerves.3

One such curious team from Stanford University and the University of Arizona recently reported a new approach using electrically conductive hydrogels to induce differentiation of human mesenchymal stem cells into neurons and oligodendrocytes in vitro.4 Their findings, published in the Journal of Materials Chemistry B, provide important proof of principle for future studies of biocompatible materials to electrically augment transplanted and endogenous cells after injury.

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Researchers have demonstrated a technique for printing thin metal oxide films at room temperature, and have used the technique to create transparent, flexible circuits that are both robust and able to function at high temperatures.

The paper, “Ambient Printing of Native Oxides for Ultrathin Transparent Flexible Circuit Boards,” was published August 15 in the journal Science.

“Creating metal oxides that are useful for electronics has traditionally required making use of specialized equipment that is slow, expensive, and operates at high temperatures,” says Michael Dickey, co-corresponding author of a paper on the work and the Camille and Henry Dreyfus Professor of Chemical and Biomolecular Engineering at North Carolina State University.

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